Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 748: 102e

Answer

This solution will be basic.

Work Step by Step

1. Analyze each type of ion in this salt, and determine which is stronger. - $N{H_4}^+$: - Weak bases have weak acids as conjugate pair. - $N{H_4}^{+}$ is the conjugate acid of $NH_3$, which is a weak base. - $N{H_4}^{+}$: Weak acid. - $ClO^-$ - Weak acids have Weak bases as conjugate pair. - $ClO^-$ is the conjugate base of $HClO$, which is a weak acid. - $ClO^-$: Weak base. Therefore, we will have to compare their constants values: - We don't have these values, but, we have the one for their conjugate pairs: $NH_3$ $K_b = 1.8 \times 10^{-5}$ $HClO$ $K_a = 2.9 \times 10^{-8}$ - $NH_3$ is the stronger conjugate pair. - Knowing the $Ka-Kb$ relation: $N{H_4}^+$ is the weaker electrolyte. ** The stronger the base, the weaker its conjugate acid, and vice versa. - Therefore, $ClO^-$ is the stronger ion, and since it is a base, the solution will be basic.
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