Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 748: 101e

Answer

This salt is acidic.

Work Step by Step

1. Analyze each type of ion in this salt, and determine which is stronger. - $C_6H_5N{H_3}^+$: - Weak bases have weak acids as conjugate pair. - $C_6H_5N{H_3}^+$ is the conjugate acid of $C_6H_5N{H_2}$, which is a weak base. - $C_6H_5N{H_3}^+$: Weak acid. - $N{O_2}^-$ - Weak acids have weak bases as conjugate pair. - $N{O_2}^-$ is the conjugate base of $HNO_2$, which is a weak acid. - $N{O_2}^-$: weak base. They both are weak electrolytes, so we will have to compare its constants values: - We don't have their constants values, but we can compare the values for its conjugate pairs: $K_b C_6H_5N{H_2} : 3.9 \times 10^{-10}$ $K_a HNO_2: 4.6 \times 10^{-4}$ - $HNO_2$ is stronger. - Based on the $Ka$ - $K_b$ relation for conjugate pair, we know that, the stronger electrolyte will have the weaker conjugate pair. - So: $N{O_2}^-$ is the weaker ion. - Therefore, $C_6H_5N{H_3}^+$ is the stronger electrolyte. - Since $C_6H_5N{H_3}^+$ is an acid, this salt will be acidic.
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