Answer
$(2b-9)^2$
Work Step by Step
The two numbers whose product is $
81(4)=324
$ and whose sum is $
-36
$ are $\{
-18,-18
\}$. Using these numbers to decompose the middle term of the trinomial results to
\begin{array}{l}
4b^2-36b+81
\\=
4b^2-18b-18b+81
\\=
(4b^2-18b)-(18b-81)
\\=
2b(2b-9)-9(2b-9)
\\=
(2b-9)(2b-9)
\\=
(2b-9)^2
.\end{array}