Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 747: 70

Answer

$Ka = 2.297\times 10^{- 6}$

Work Step by Step

1. Drawing the equilibrium (ICE) table, we get these concentrations at equilibrium:** The image is in the end of this answer. -$[H_3O^+] = [A^-] = x$ -$[HA] = [HA]_{initial} - x$ 2.Calculate the hydronium concentration: $[H_3O^+] = 10^{-pH}$ $[H_3O^+] = 10^{- 3.29}$ $[H_3O^+] = 5.129 \times 10^{- 4}$ 3. Write the Ka equation, and find its value: $Ka = \frac{[H_3O^+][A^-]}{ [HA]}$ $Ka = \frac{x^2}{[InitialHA] - x}$ $Ka = \frac{( 5.129\times 10^{- 4})^2}{ 0.115- 5.129\times 10^{- 4}}$ $Ka = \frac{ 2.63\times 10^{- 7}}{ 0.1145}$ $Ka = 2.297\times 10^{- 6}$
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