Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Cumulative Problems - Page 750: 140d

Answer

$pH = 1.18$

Work Step by Step

- Identify the electrolytes: $HClO_4$: Strong acid. $RbOH$: Strong base. 1. Find the hydronium ion concentration produced by the acid. Strong acid: $[H_3O^+] = [HClO_4]_{initial} = 0.088M$ 2. Find the hydroxide ion concentration produced by the base. Strong base: $[OH^-] = [RbOH]_{initial} = 0.022M$ 3. Calculate their difference. $0.088M - 0.022M = 0.066M$ - Since $H_3O^+$ had greater concentration, there is $0.066M$ $H_3O^+$ in excess. 4. Calculate the pH Value $pH = -log[H_3O^+]$ $pH = -log( 0.066)$ $pH = 1.18$
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