Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Cumulative Problems - Page 750: 140c

Answer

$pH = 12.87$

Work Step by Step

1. Identify the significant electrolytes: - $RbOH$: Strong base. - $Na^+$: Insignificant. - $HC{O_3}^-$: Weak base. 2. Calculate the $K_b$ for the weak base: - Since $HC{O_3}^-$ is the conjugate base of $H_2CO_3$ , we can calculate its kb by using this equation: $K_a * K_b = K_w = 10^{-14}$ $ 4.3\times 10^{- 7} * K_b = 10^{-14}$ $K_b = \frac{10^{-14}}{ 4.3\times 10^{- 7}}$ $K_b = 2.326\times 10^{- 8}$ 3. Since it has a low $K_b$ value, we can ignore it, and calculate the pH just considering $RbOH$ $0.075M$ $pOH = -log[OH^-]$ $pOH = -log( 0.075)$ $pOH = 1.13$ $pH + pOH = 14$ $pH + 1.13 = 14$ $pH = 12.87$
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