Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 14 - Sections 14.1-14.9 - Exercises - Problems by Topic - Page 690: 44

Answer

$$K_c = 1.8 \times 10^-2$$

Work Step by Step

1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_C = \frac{[Products]}{[Reactants]} = \frac{[ SO_2 ][ Cl_2 ]}{[ SO_2Cl_2 ]}$$ 2. At equilibrium, these are the concentrations of each compound: $ [ SO_2Cl_2 ] = 0.020 \space M - x$ $ [ SO_2 ] = 0 \space M + x$ $ [ Cl_2 ] = 0 \space M + x$ As we know, at equilibrium: $[Cl_2 ] = 1.2 \times 10^{-2} \space M$ Thus, $x = 1.2 \times 10^{-2}$. Substituting: $ [ SO_2 ] = 1.2 \times 10^{-2} \space M$ $ [ SO_2Cl_2 ] = 8.0 \times 10^{-3} \space M$ $$K_c = \frac{(1.2 \times 10^{-2}) (1.2 \times 10^{-2} )}{( 8.0 \times 10^{-3})} = 1.8 \times 10^{-2}$$
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