Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 14 - Sections 14.1-14.9 - Exercises - Problems by Topic - Page 690: 43

Answer

$$K_c = 3.3 \times 10^2$$

Work Step by Step

1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_C = \frac{[Products]}{[Reactants]} = \frac{[ FeSCN^{2+} ]}{[ Fe^{3+} ][ SCN^- ]}$$ 2. At equilibrium, these are the concentrations of each compound: $ [ Fe^{3+} ] = 1.0 \times 10^{-3} \space M - x$ $ [ SCN^- ] = 8.0 \times 10^{-4} \space M - x$ $ [ FeSCN^{2+} ] = 0 \space M + x$ As we know, at equilibrium: $[ FeSCN^{2+} ] = 1.7 \times 10^{-4} \space M$ Thus, $x = 1.7 \times 10^{-4}$. Substituting: $ [ Fe^{3+} ] = 8.3 \times 10^{-4} \space M$ $ [ SCN^- ] = 6.3 \times 10^{-4} \space M$ $$K_c = \frac{( 1.7 \times 10^{-4} )}{( 8.3 \times 10^{-4})( 6.3 \times 10^{-4})} = 3.3 \times 10^2$$
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