Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 14 - Sections 14.1-14.9 - Exercises - Problems by Topic - Page 690: 41

Answer

$$K_P = 18$$

Work Step by Step

1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_P = \frac{[Products]}{[Reactants]} = \frac{P_{ B } ^{ 2 }}{P_{ A }}$$ 2. At equilibrium, these are the concentrations of each compound: $ P_{ A } = 1.32 - x$ $ P_{ B } = 0 + 2x$ - We know that, at equilibrium, $P_A = 0.25$, thus: $0.25 = 1.32 -x$ $x = 1.07$ $P_B = 2(1.07) = 2.14$ $$K_P = \frac{2.14^2}{0.25} = 18$$
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