Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 14 - Sections 14.1-14.9 - Exercises - Problems by Topic - Page 690: 40

Answer

$$P_{SO_2Cl_2} = 2.32 \times 10^{-5} \space atm = 1.76 \times 10^{-2} \space torr$$

Work Step by Step

- Convert all the pressures to atm: 1 atm = 760 torr. $P_{SO_2} = 0.180 \space atm$ $P_{Cl_2} = 0.375 \space atm$ 1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_P = \frac{[Products]}{[Reactants]} = \frac{P_{ SO_2 }P_{ Cl_2 }}{P_{ SO_2Cl_2 }}$$ 2. Solve for the missing concentration: $$ P_{SO_2Cl_2} = \frac{P_{ SO_2 } P_{ Cl_2 } }{ K_P}$$ 3. Evaluate the expression: $$ P_{SO_2Cl_2} = \frac{( 0.180 )( 0.375 )}{(2.91 \times 10^3)} $$ $$P_{SO_2Cl_2} = 2.32 \times 10^{-5} \space atm = 1.76 \times 10^{-2} \space torr$$
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