Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 16 - Sections 16.1-16.8 - Exercises - Problems by Topic - Page 807: 90b

Answer

$ K_{sp} (Ag_2S{O_3}) = (1.49 \times 10^{-14})$

Work Step by Step

1. Write the $K_{sp}$ expression: $ Ag_2S{O_3}(s) \lt -- \gt 2Ag^{+}(aq) + 1S{O_3}^{2-}(aq)$ $ K_{sp} = [Ag^{+}]^ 2[S{O_3}^{2-}]^ 1$ 2. Determine the ions concentrations: $[Ag^{+}] = [Ag_2S{O_3}] * 2 = [1.55 \times 10^{-5}] * 2 = 3.1 \times 10^{-5}$ $[S{O_3}^{2-}] = [Ag_2S{O_3}] * 1 = 1.55 \times 10^{-5}$ 3. Calculate the $K_{sp}$: $ K_{sp} = (3.1 \times 10^{-5})^ 2 \times (1.55 \times 10^{-5})^ 1$ $ K_{sp} = (9.61 \times 10^{-10}) \times (1.55 \times 10^{-5})$ $ K_{sp} = (1.49 \times 10^{-14})$
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