Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 16 - Sections 16.1-16.8 - Exercises - Problems by Topic - Page 804: 39c

Answer

$pH = 4.61$

Work Step by Step

For the acid: 1. Calculate the molar mass: 1.01* 1 + 12.01* 2 + 1.01* 3 + 16* 2 = 60.06g/mol 2. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 10}{ 60.06}$ $n(moles) = 0.1665$ 3. Find the concentration in mol/L: $C(mol/L) = \frac{n(moles)}{volume(L)}$ $ C(mol/L) = \frac{ 0.1665}{ 0.15} $ $C(mol/L) = 1.11$ For the base: 4. Calculate the molar mass: 22.99* 1 + 12.01* 2 + 1.01* 3 + 16* 2 ) = 82.04g/mol 5. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 10}{ 82.04}$ $n(moles) = 0.1219$ 6. Find the concentration in mol/L: $C(mol/L) = \frac{n(moles)}{volume(L)}$ $ C(mol/L) = \frac{ 0.1219}{ 0.15} $ $C(mol/L) = 0.8126$ 7. Calculate the pKa Value $pKa = -log(Ka)$ $pKa = -log( 1.8 \times 10^{- 5})$ $pKa = 4.745$ 8. Using the Henderson–Hasselbalch equation: $pH = pKa + log(\frac{[Base]}{[Acid]})$ $pH = 4.745 + log(\frac{0.813}{1.11})$ $pH = 4.745 + log(0.7324)$ $pH = 4.745 + (-0.1352)$ $pH = 4.61$
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