Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 16 - Sections 16.1-16.8 - Exercises - Problems by Topic - Page 804: 29b

Answer

$pH = 9.107$

Work Step by Step

1. Draw the ICE table (It is in the end of this answer) 2. Calculate "x" using the $K_b$ expression: $ 1.76\times 10^{- 5} = \frac{[N{H_4}^+][OH^-]}{[N{H_3}]}$ $ 1.76\times 10^{- 5} = \frac{ (0.22 + x )* x}{ 0.16 - x}$ Considering 'x' has a very small value. $ 1.76\times 10^{- 5} = \frac{ 0.22 * x}{ 0.16}$ $ 1.76\times 10^{- 5} = 1.375x$ $\frac{ 1.76\times 10^{- 5}}{ 1.375} = x$ $x = 1.28\times 10^{- 5}$ Percent ionization: $\frac{ 1.28\times 10^{- 5}}{ 0.16} \times 100\% = 8\times 10^{- 3}\%$ - Greater than $5\%$, correct approximation. $[OH^-] = x$ 3. Calculate the pH: $pOH = -log[OH^-]$ $pOH = -log( 1.28 \times 10^{- 5})$ $pOH = 4.893$ $pH + pOH = 14$ $pH + 4.893 = 14$ $pH = 9.107$
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