Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 4 - Exercises - Page 188: 47

Answer

2.91 g of $CO$ remain in the mixture.

Work Step by Step

1. Identify the limiting reactant. - Calculate or find the molar mass for $ Fe_2O_3 $: $ Fe_2O_3 $ : ( 55.85 $\times$ 2 )+ ( 16.00 $\times$ 3 )= 159.7 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 22.55 \space g \times \frac{1 \space mole}{ 159.7 \space g} = 0.1412 \space mole$$ - Calculate or find the molar mass for $ CO $: $ CO $ : ( 12.01 $\times$ 1 )+ ( 16.00 $\times$ 1 )= 28.01 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 14.78 \space g \times \frac{1 \space mole}{ 28.01 \space g} = 0.528 \space mole$$ Find the amount of product if each reactant is completely consumed. $$ 0.1412 \space mole \space Fe_2O_3 \times \frac{ 2 \space moles \ Fe }{ 1 \space mole \space Fe_2O_3 } = 0.2824 \space mole \space Fe $$ $$ 0.5277 \space mole \space CO \times \frac{ 2 \space moles \ Fe }{ 3 \space moles \space CO } = 0.3518 \space mole \space Fe $$ Since the reaction of $ Fe_2O_3 $ produces less $ Fe $ for these quantities, it is the limiting reactant. 2. Find the amount of $ CO $ consumed: $$ 0.1412 \space moles \space Fe_2O_3 \times \frac{ 3 \space mol \space CO }{ 1 \space mol \space Fe_2O_3 } = 0.4236 \space mol \space CO $$ 3. Subtract that amount from the amount in the reaction mixture. $$Excess = 0.528 - 0.4236 = 0.104 \space mol \space CO $$ 4. Using its molar mass, find the amount in grams: $$ 0.104 \space mole \times \frac{ 28.01 \space g}{1 \space mole} = 2.91 \space g$$
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