Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 4 - Exercises - Page 188: 45

Answer

a. 2.5 g of $AlCl_3$ b. 31.1 g of $AlCl_3$ c. 1.16 g of $AlCl_3$

Work Step by Step

a. - Calculate or find the molar mass for $ Al $: $ Al $ : 26.98 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 2.0 \space g \times \frac{1 \space mole}{ 26.98 \space g} = 0.074 \space mole$$ - Calculate or find the molar mass for $ Cl_2 $: $ Cl_2 $ : ( 35.45 $\times$ 2 )= 70.90 g/mol - Using the molar mass as a conversion factor, find the amount in moles: $$ 2.0 \space g \times \frac{1 \space mole}{ 70.90 \space g} = 0.028 \space mole$$ Find the amount of product if each reactant is completely consumed. $$ 0.074 \space mole \space Al \times \frac{ 2 \space moles \ AlCl_3 }{ 2 \space moles \space Al } = 0.074 \space mole \space AlCl_3 $$ $$ 0.028 \space mole \space Cl_2 \times \frac{ 2 \space moles \ AlCl_3 }{ 3 \space moles \space Cl_2 } = 0.019 \space mole \space AlCl_3 $$ Since the reaction of $ Cl_2 $ produces less $ AlCl_3 $ for these quantities, it is the limiting reactant. - Calculate or find the molar mass for $ AlCl_3 $: $ AlCl_3 $ : ( 26.98 $\times$ 1 )+ ( 35.45 $\times$ 3 )= 133.33 g/mol - Using the molar mass as a conversion factor, find the mass in g: $$ 0.019 \space mole \times \frac{ 133.33 \space g}{1 \space mole} = 2.5 \space g$$ b. - Using the molar mass as a conversion factor, find the amount in moles: $$ 7.5 \space g \times \frac{1 \space mole}{ 26.98 \space g} = 0.28 \space mole$$ - Using the molar mass as a conversion factor, find the amount in moles: $$ 24.8 \space g \times \frac{1 \space mole}{ 70.90 \space g} = 0.350 \space mole$$ Find the amount of product if each reactant is completely consumed. $$ 0.28 \space mole \space Al \times \frac{ 2 \space moles \ AlCl_3 }{ 2 \space moles \space Al } = 0.28 \space mole \space AlCl_3 $$ $$ 0.350 \space mole \space Cl_2 \times \frac{ 2 \space moles \ AlCl_3 }{ 3 \space moles \space Cl_2 } = 0.233 \space mole \space AlCl_3 $$ Since the reaction of $ Cl_2 $ produces less $ AlCl_3 $ for these quantities, it is the limiting reactant. - Using the molar mass as a conversion factor, find the mass in g: $$ 0.233 \space mole \times \frac{ 133.33 \space g}{1 \space mole} = 31.1 \space g$$ c. - Using the molar mass as a conversion factor, find the amount in moles: $$ 0.235 \space g \times \frac{1 \space mole}{ 26.98 \space g} = 0.00871 \space mole$$ - Using the molar mass as a conversion factor, find the amount in moles: $$ 1.15 \space g \times \frac{1 \space mole}{ 70.90 \space g} = 0.0162 \space mole$$ Find the amount of product if each reactant is completely consumed. $$ 0.00871 \space mole \space Al \times \frac{ 2 \space moles \ AlCl_3 }{ 2 \space moles \space Al } = 0.00871 \space mole \space AlCl_3 $$ $$ 0.0162 \space mole \space Cl_2 \times \frac{ 2 \space moles \ AlCl_3 }{ 3 \space moles \space Cl_2 } = 0.0108 \space mole \space AlCl_3 $$ Since the reaction of $ Al $ produces less $ AlCl_3 $ for these quantities, it is the limiting reactant. - Using the molar mass as a conversion factor, find the mass in g: $$ 0.00871 \space mole \times \frac{ 133.33 \space g}{1 \space mole} = 1.16 \space g$$
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