Answer
$$\frac{1}{2}$$
Work Step by Step
\begin{align*}
\lim _{\theta \rightarrow \frac{\pi}{4}}\left(\frac{1}{\tan \theta-1}-\frac{2}{\tan ^{2} \theta-1}\right)&=\lim _{\theta \rightarrow \frac{\pi}{4}} \frac{(\tan \theta+1)-2}{(\tan \theta+1)(\tan \theta-1)}\\
&=\lim _{\theta \rightarrow \frac{\pi}{4}} \frac{1}{\tan \theta+1}\\
&=\frac{1}{2}
\end{align*}