Answer
a) $Ni^{2+}, 2\ Cl^-$
b) $Cr^{3+}, 3\ NO_3^-$
c) $Pb^{2+}, 2\ NO_3^-$
d) Insoluble
Work Step by Step
a) $Ni^{2+}, 2\ Cl^-$
Chlorides are usually soluble; nickel (||)'s is not an exception.
b) $Cr^{3+}, 3\ NO_3^-$
Nitrates are almost always soluble.
c) $Pb^{2+}, 2\ NO_3^-$
Nitrates are almost always soluble.
d) Insoluble
Sulfates are usually soluble, but barium's is an exception.