Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic A - Matter - Exercises - Page 23: A.2(a)

Answer

(i) Oxidation number of chlorine is -1 Oxidation number of magnesium is +2 (ii) Oxidation number of oxygen is -2 Oxidation number of iron is +2 (iii) Oxidation number of chlorine is -1 Oxidation number of mercury is +1

Work Step by Step

(i) Since Chlorine is a halogen, it normally has only one stable ion, Cl$^{-}$, making its oxidation number -1. Because MgCl$_{2}$ is uncharged, the magnesium has an oxidation number of +2, to balance the two Cl$^{-}$ charges. (ii). The oxidation number of oxygen in almost all molecules is -2. To balance the molecule's charge, the oxidation number of iron must be +2. (iii). As a halogen, the oxidation number of chlorine is -1. To balance the molecule's charge, the oxidation number of mercury must be +1.
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