Answer
$22.74\ g\ Br_2$
$25.31\ g\ Al_2Br_6$
Work Step by Step
Number of moles of aluminum:
$2.56\ g\div26.982\ g/mol=0.0949\ mol$
From stoichiometry:
$0.0949\ mol\times3/2\times159.808\ g/mol\ Br_2=22.74\ g\ Br_2$
$0.0949\ mol\times1/2\times 533.387\ g/mol\ Al_2Br_6=25.31\ g\ Al_2Br_6$