Physics: Principles with Applications (7th Edition)

Published by Pearson
ISBN 10: 0-32162-592-7
ISBN 13: 978-0-32162-592-2

Chapter 27 - Early Quantum Theory and Models of the Atom - Problems - Page 800: 64

Answer

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Work Step by Step

We know that the electrostatic potential energy of an electron is given by $$PE=-\dfrac{1}{4\pi\varepsilon_0}\times \dfrac{\pi Z^2e^4m}{n^2h^2\varepsilon_0 }$$ The charge is negative; $$PE= \dfrac{- Z^2e^4m}{4n^2h^2\varepsilon_0^2 }\tag 1$$ We know its total energy is given by $$E=KE+PE$$ Thus, $$KE=E-PE= \dfrac{- Z^2e^4m}{8n^2h^2\varepsilon_0^2 }- \dfrac{- Z^2e^4m}{4n^2h^2\varepsilon_0^2 }$$ $$KE= \dfrac{- Z^2e^4m}{8n^2h^2\varepsilon_0^2 }+ \dfrac{ Z^2e^4m}{4n^2h^2\varepsilon_0^2 }=\dfrac{- Z^2e^4m+2 Z^2e^4m}{8n^2h^2\varepsilon_0^2 }$$ $$KE =\dfrac{ Z^2e^4m}{8n^2h^2\varepsilon_0^2 }\tag 2$$ Dividing (1) by (2); $$\bigg|\dfrac{PE}{KE}\bigg|=\left|\dfrac{ \dfrac{- Z^2e^4m}{4n^2h^2\varepsilon_0^2 }}{\dfrac{ Z^2e^4m}{8n^2h^2\varepsilon_0^2 }}\right|$$ $$ \dfrac{PE}{KE} = \dfrac{ Z^2e^4m}{4n^2h^2\varepsilon_0^2 }\times \dfrac{8n^2h^2\varepsilon_0^2 }{ Z^2e^4m}=2 $$ Hence, $$\boxed{PE=\color{red}{\bf 2}KE}$$ Therefore, the electrostatic potential energy of an electron in any Bohr orbit of a hydrogen atom is twice the magnitude of its kinetic energy in the same orbit.
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