Answer
$alpha=90^{\circ}$ for any value of $\theta_{i1}$
Work Step by Step
Let PQRS is parallelogram.
So, Angle PQR + Angle QRS = $180^{\circ}$
Therefore, $(\theta_{i1}+\theta_{r1})+(\theta_{i2}+\theta_{r2})=180^{\circ}$
or, $2\theta_{i1}+2\theta_{r2}=180^{\circ}$
$\theta_{i1}+\theta_{r2}=90^{\circ}$
or, $\theta_{i1}+alpha-\theta_{i1}=90^{\circ}$
Therefore, $alpha=90^{\circ}$
Hence, for $alpha=90^{\circ}$ and for any value of $\theta_{i1}$ the ray will reflect in the direction from where came i.e. parallel to the incident ray.