Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic b - Energy - Exercises - Page 25: B.22(b)

Answer

For $Hg_2$, $v_{mean}\approx 1.25\times10^{4}$ $cm/s$ For $H_2$, $v_{mean}\approx 1.78\times10^{5}$ $cm/s$

Work Step by Step

According to the Maxwell–Boltzmann distribution, the average speed $(v_{mean})$ of the gas molecules is expressed as $v_{mean}=\sqrt {\frac{8RT}{\pi M}}$ where $T$ is the temperature and $M$ is the molar mass of the molecules. As the temperature is not specified here, we have to calculate $v_{mean}$ at room temperature $T=298$ $K$. The molar mass of $Hg_{2}$ molecules is $M=401.18$ $g$ For $T=298$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 298}{\pi\times 401.18}}$ $cm/s$ $v_{mean}\approx 1.25\times10^{4}$ $cm/s$ The molar mass of $H_2$ molecules is $M=2$ $g$ For $T=298$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 298}{\pi\times 2}}$ $cm/s$ $v_{mean}\approx 1.78\times10^{5}$ $cm/s$
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