Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic b - Energy - Exercises - Page 25: B.21(a)

Answer

At $0^{\circ}C$, $v_{mean}\approx 4.54\times10^{4}$ $cm/s$ At $40^{\circ}C$, $v_{mean}\approx 4.86\times10^{4}$ $cm/s$

Work Step by Step

According to the Maxwell–Boltzmann distribution, the average speed $(v_{mean})$ of the gas molecules is expressed as $v_{mean}=\sqrt {\frac{8RT}{\pi M}}$ where $T$ is the temperature and $M$ is the molar mass of the molecules. The molar mass of $N_2$ molecules is $M=28$ $g$ For $T=(0+273)$ $K$ $=273$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 273}{\pi\times 28}}$ $cm/s$ $v_{mean}\approx4.54\times10^{4}$ $cm/s$ For $T=(40+273)$ $K$ $=313$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 313}{\pi\times 28}}$ $cm/s$ $v_{mean}\approx 4.86\times10^{4}$ $cm/s$
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