Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic b - Energy - Exercises - Page 25: B.21(b)

Answer

At $20^{\circ}C$, $v_{mean}\approx 3.75\times10^{4}$ $cm/s$ At $30^{\circ}C$, $v_{mean}\approx 3.82\times10^{4}$ $cm/s$

Work Step by Step

According to the Maxwell–Boltzmann distribution, the average speed $(v_{mean})$ of the gas molecules is expressed as $v_{mean}=\sqrt {\frac{8RT}{\pi M}}$ where $T$ is the temperature and $M$ is the molar mass of the molecules. The molar mass of $CO_2$ molecules is $M=44$ $g$ For $T=(20+273)$ $K$ $=293$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 293}{\pi\times 44}}$ $cm/s$ $v_{mean}\approx 3.75\times10^{4}$ $cm/s$ For $T=(30+273)$ $K$ $=303$ $K$ $v_{mean}=\sqrt {\frac{8\times 8.3145\times 10^{7}\times 303}{\pi\times 44}}$ $cm/s$ $v_{mean}\approx 3.82\times10^{4}$ $cm/s$
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