Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 16 - Thermodynamics: Directionality of Chemical Reactions - Questions for Review and Thought - Topical Questions - Page 737e: 76a

Answer

Requires work to be done.

Work Step by Step

$\Delta_{r}G^{\circ}=\Sigma n_{p}\Delta_{f}G^{\circ}(products)-\Sigma n_{r}\Delta _{f}G^{\circ}(reactants)$ $=[2\Delta_{f}G^{\circ}(Al,s)+\frac{3}{2}\Delta_{f}G^{\circ}(O_{2},g)]-[\Delta_{f}G^{\circ}(Al_{2}O_{3},s)]$ $=[2(0\,kJ/mol)+\frac{3}{2}(0\,kJ/mol)]-(-1582.3\,kJ/mol)$ $=1582.3\,kJ/mol$ As $\Delta _{r}G^{\circ}$ is positive, work needs to be done for this reaction to occur. At least 1582.3 kJ/mol work is required.
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