Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 16 - Thermodynamics: Directionality of Chemical Reactions - Questions for Review and Thought - Topical Questions - Page 737d: 57

Answer

$\Delta _{r}G^{\circ}=462.28\,kJ$ This reaction is not a good choice to produce $Si$.

Work Step by Step

$\Delta_{r}G^{\circ}=\Sigma n_{p}\Delta_{f}G^{\circ}(products)-\Sigma n_{r}\Delta _{f}G^{\circ}(reactants)$ $=[1\,mol\times\Delta_{f}G^{\circ}(Si,s)+1\,mol\times\Delta_{f}G^{\circ}(CO_{2},g)]-[1\,mol\times\Delta_{f}G^{\circ}(SiO_{2},s)+1\,mol\times\Delta_{f}G^{\circ}(C,s)]$ $=[(0)+(-394.359\,kJ)]-[(-856.64\,kJ)+(0)]$ $=462.28\,kJ$ As $\Delta _{r}G^{\circ}$ is positive, the reaction is reactant-favored (nonspontaneous) . Therefore, this reaction is not a good choice to produce silicon.
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