Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Questions for Review and Thought - Topical Questions - Page 693c: 58

Answer

$ K_{sp} (PbCl_2) = (1.7 \times 10^{-5})$

Work Step by Step

1. Write the $K_{sp}$ expression: $ PbCl_2(s) \lt -- \gt 1Pb^{2+}(aq) + 2Cl^{-}(aq)$ $ K_{sp} = [Pb^{2+}]^ 1[Cl^{-}]^ 2$ 2. Determine the ions concentrations: $[Pb^{2+}] = [PbCl_2] * 1 = [0.0161] * 1 = 0.0161$ $[Cl^{-}] = [PbCl_2] * 2 = 0.0323$ 3. Calculate the $K_{sp}$: $ K_{sp} = (0.0161)^ 1 \times (0.0323)^ 2$ $ K_{sp} = (0.0161) \times (1.05 \times 10^{-3})$ $ K_{sp} = (1.701 \times 10^{-5})$
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