Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Questions for Review and Thought - Topical Questions - Page 693c: 54

Answer

$ K_{sp} (CaSO_4) = (2.2 \times 10^{-4})$

Work Step by Step

1. Calculate the molar mass: 40.08* 1 + 32.07* 1 + 16* 4 = 136.15g/mol 2. Calculate the number of moles $n(moles) = \frac{mass(g)}{mm(g/mol)}$ $n(moles) = \frac{ 2.03}{ 136.15}$ $n(moles) = 0.01491$ 3. Find the concentration in mol/L: $C(mol/L) = \frac{n(moles)}{volume(L)}$ $ C(mol/L) = \frac{ 0.01491}{ 1} $ $C(mol/L) = 0.01491$ 4. Write the $K_{sp}$ expression: $ CaSO_4(s) \lt -- \gt 1Ca^{2+}(aq) + 1S{O_4}^{2-}(aq)$ $ K_{sp} = [Ca^{2+}]^ 1[S{O_4}^{2-}]^ 1$ 5. Determine the ions concentrations: $[Ca^{2+}] = [CaSO_4] * 1 = [0.01491] * 1 = 0.01491$ $[S{O_4}^{2-}] = [CaSO_4] * 1 = 0.01491$ 6. Calculate the $K_{sp}$: $ K_{sp} = (0.01491)^ 1 \times (0.01491)^ 1$ $ K_{sp} = (0.01491) \times (0.01491)$ $ K_{sp} = (2.222 \times 10^{-4})$
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