Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 18 - Questions and Problems - Page 869: 18.29

Answer

(a) $-1139\,kJ/mol$ (b) $-140.0\,kJ/mol$ (c) $-2935\,kJ/mol$

Work Step by Step

Recall: $\Delta G^{\circ}=\Sigma n_{p}\Delta G_{f}^{\circ}(products)-\Sigma n_{r}\Delta G_{f}^{\circ}(reactants)$ (a) $\Delta G^{\circ}=[2\Delta G_{f}^{\circ}(MgO,s)]-[2\Delta G_{f}^{\circ}(Mg,s)+\Delta G_{f}^{\circ}(O_{2},g)]$ $=[2(-569.6\,kJ/mol)]-[2(0)+(0)]$ $=-1139\,kJ/mol$ (b) $\Delta G^{\circ}=[2\Delta G_{f}^{\circ}(SO_{3},g)]-[2\Delta G_{f}^{\circ}(SO_{2},g)+\Delta G_{f}^{\circ}(O_{2},g)]$ $=[2(-370.4\,kJ/mol)]-[2(-300.4)+(0)]$ $=-140.0\,kJ/mol$ (c) $\Delta G^{\circ}=[4\Delta G_{f}^{\circ}(CO_{2},g)+6\Delta G_{f}^{\circ}(H_{2}O,l)]-[2\Delta G_{f}^{\circ}(C_{2}H_{6},g)+7\Delta G_{f}^{\circ}(O_{2},g)]$ $=[4(-394.4\,kJ/mol)+6(-237.2\,kJ/mol)]-[2(-32.89)+7(0)]$ $=-2935\,kJ/mol$
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