Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 18 - Questions and Problems - Page 869: 18.28

Answer

(a) $173.4\,kJ/mol$ (b) $8.6\,kJ/mol$ (c) $-2470.4\,kJ/mol$

Work Step by Step

Recall: $\Delta G^{\circ}=\Sigma n_{p}\Delta G_{f}^{\circ}(products)-\Sigma n_{r}\Delta G_{f}^{\circ}(reactants)$ (a) $\Delta G^{\circ}=[2\Delta G_{f}^{\circ}(NO,g)]-[\Delta G_{f}^{\circ}(N_{2},g)+\Delta G_{f}^{\circ}(O_{2},g)]$ $=[2(86.7\,kJ/mol)]-[(0\,kJ/mol)+(0\,kJ/mol)]$ $=173.4\,kJ/mol$ (b) $\Delta G^{\circ}=[\Delta G_{f}^{\circ}(H_{2}O,g)]-[\Delta G_{f}^{\circ}(H_{2}O,l)]$ $=(-228.6\,kJ/mol)-(-237.2\,kJ/mol)$ $=8.6\,kJ/mol$ (c) $\Delta G^{\circ}=[4\Delta G_{f}^{\circ}(CO_{2},g)+2\Delta G_{f}^{\circ}(H_{2}O,l)]-[2\Delta G_{f}^{\circ}(C_{2}H_{2},g)+5\Delta G_{f}^{\circ}(O_{2},g)]$ $=[4(-394.4\,kJ/mol)+2(-237.2\,kJ/mol)]-[2(209.2\,kJ/mol)+5(0)]$ $=-2470.4\,kJ/mol$
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