Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 17 - Questions and Problems - Page 827: 17.62

Answer

$5.225 \times 10^{-6} g$

Work Step by Step

Since $Ca(NO_3)_2$ is an ionic soluble salt, the concentration of calcium ions will be equal to $0.050$ M. 1. Write the $K_{sp}$ expression: $ CaCO_3(s) \lt -- \gt 1Ca^{2+}(aq) + 1CO_3^{2-}(aq)$ $8.8 \times 10^{-9} = [Ca^{2+}]^ 1[CO_3^{2-}]^ 1$ $8.8 \times 10^{-9} = (0.05 + S)^ 1( 1S)^ 1$ 2. Find the molar solubility. Since 'S' has a very small value, we can approximate: $[Ca^{2+}] = 0.05$ $8.7 \times 10^{-9}= (0.05)^ 1 \times ( 1S)^ 1$ $ \frac{8.7 \times 10^{-9}}{0.05} = ( 1S)^ 1$ $1.74 \times 10^{-7} = S$ 3. Find the number of moles: ** $3 \times 10^2$ mL = $300mL$ = $300 \times 10^{-3}$ L = 0.300 L $Concentration(M) = \frac{n(mol)}{V(L)}$ $1.74 \times 10^{-7} = \frac{n(mol)}{0.3}$ $1.74 \times 10^{-7} * 0.3 = n(mol)$ $5.22 \times 10^{-8} moles = n(mol)$ 4. Determine the molar mass of this compound ($CaCO_3$): 40.08* 1 + 12.01* 1 + 16* 3 ) = 100.09g/mol 5. Calculate the mass $mm(g/mol) = \frac{mass(g)}{n(mol)}$ $mm(g/mol) * n(mol) = mass(g)$ $ 100.09 * 5.22 \times 10^{-8} = mass(g)$ $5.225 \times 10^{-6} = mass(g)$
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