Answer
Since $\vert m_l \vert \gt l$, these quantum numbers are not possible.
Work Step by Step
For each $n$, the values of $l$ can be $~~l = 0, 1, 2,...,(n-1)$
For each $l,$ the values of $m_l$ can be $~~m_l = 0, \pm 1, \pm 2,...,\pm l$
In this case: $~~n = 4, ~~l=3, ~~m_l = -4$
However, when $l = 3,$ the values of $m_l$ can be $~~m_l = 0, \pm 1, \pm 2, \pm 3$
Since $\vert m_l \vert \gt l$, these quantum numbers are not possible.
