Answer
The car cannot negotiate the curve safely.
Work Step by Step
$83km/hr=23.1m/s$
$r=0.4km=400m$
Tires can support $a=1.25m/s^{2}$
But, $a_{c}=\frac{v^{2}}{r}=\frac{23.1^{2}}{400}=1.334m/s^{2}$ which is greater than what the tires can support.
Hence, the car cannot negotiate the curve safely.