Physical Chemistry: Thermodynamics, Structure, and Change

Published by W. H. Freeman
ISBN 10: 1429290196
ISBN 13: 978-1-42929-019-7

Foundations - Topic B - Energy - Discussion Questions - Page 24: B.6

Answer

The main features of the Maxwell–Boltzmann distribution of speeds are given bellow: 1. The distribution of populations is an exponential function of energy and temperature. 2. At a high temperature more energy levels are occupied than at a low temperature. 3. More levels are significantly populated if they are close together in comparison with $kT$ (like rotational and translational states), than if they are far apart (like vibrational and electronic states).

Work Step by Step

The main features of the Maxwell–Boltzmann distribution of speeds are given bellow: 1. The distribution of populations is an exponential function of energy and temperature. 2. At a high temperature more energy levels are occupied than at a low temperature. 3. More levels are significantly populated if they are close together in comparison with $kT$ (like rotational and translational states), than if they are far apart (like vibrational and electronic states).
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