Chemistry and Chemical Reactivity (9th Edition)

Published by Cengage Learning
ISBN 10: 1133949649
ISBN 13: 978-1-13394-964-0

Chapter 5 Principles of Chemical Reactivity: Energy and Chemical Reactions - Study Questions - Page 217a: 31

Answer

$V2 = 1.146m^{3}$

Work Step by Step

data: initial volume= $V1= 1.50l= 0.0015m^{3}$ $pressure= P= 1.22 × 10^{5} Pa$ heat absorbed = $q = 1.25KJ=1.25× 10^{3}$ change in internal energy = $ΔU = 1.11KJ=1.11× 10^{3}$ to find: final volume = V2 = ? formula used: Δ V = V2-V1 ΔU = q + PΔ V solution: PΔ V = ΔU - q $PΔ V = 1.11× 10^{3} - 0.0015m^{3}$ $PΔ V = -1.4×10^{5}$ $Δ V = -1.4×10^{5}/1.22 × 10^{5} Pa$ $Δ V = 1.147m^{3}$ as Δ V = V2-V1 V2 = ΔV - V1 $V2 = 1.147m^{3} - 0.0015m^{3}$ $V2 = 1.146m^{3}$
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