Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 15 - Sections 15.1-15.12 - Exercises - Problems by Topic - Page 746: 57c

Answer

$[H_3O^+] = 0.072M$ $[OH^-] = 1.389 \times 10^{- 13}M$ $pH = 1.143$

Work Step by Step

1. To calculate the $[H_3O^+]$ of a mixture of 2 strong acids, all we need to do is to sum the concentrations: $HBr$ is a strong acid, therefore: $[H_3O^+]$ from $ HBr = [HBr] = 0.052M$ $HNO_3$ is a strong acid, therefore: $[H_3O^+]$ from $HNO_3 = [HNO_3] = 0.020M$ $0.052M + 0.020M = 0.072M = Total [H_3O^+]$ 2. Calculate the pH value $pH = -log[H_3O^+]$ $pH = -log( 0.072)$ $pH = 1.143$ 3. Use $K_w$ to calculate the hydroxide concentration: $[H_3O^+] * [OH^-] = Kw = 10^{-14}$ $ 7.2 \times 10^{- 2} * [OH^-] = 10^{-14}$ $[OH^-] = \frac{10^{-14}}{ 7.2 \times 10^{- 2}}$ $[OH^-] = 1.389 \times 10^{- 13}$
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