Chemistry (4th Edition)

Published by McGraw-Hill Publishing Company
ISBN 10: 0078021529
ISBN 13: 978-0-07802-152-7

Chapter 15 - Questions and Problems - Page 709: 15.48

Answer

$[H_2] = 0.05 M$ $[CO_2] = 0.05 M$ $[H_2O] = 0.11 M$ $[CO] = 0.11 M$

Work Step by Step

- Calculate all the concentrations: $$[H_2] = ( 0.80 )/(5.0) = 0.16 M$$ $$[CO_2] = ( 0.80 )/(5.0) = 0.16 M$$ 1. Write the equilibrium constant expression: - The exponent of each concentration is equal to its balance coefficient. $$K_C = \frac{[Products]}{[Reactants]} = \frac{[ H_2O ][ CO ]}{[ H_2 ][ CO_2 ]}$$ 2. At equilibrium, these are the concentrations of each compound: $ [ H_2 ] = 0.16 \space M - x$ $ [ CO_2 ] = 0.16 \space M - x$ $ [ H_2O ] = x$ $ [ CO ] = x$ $$4.2 = \frac{(0 + x)(0 + x)}{(0.16 - x)(0.16 - x)}$$ x = 0.11 M $[H_2] = 0.05 M$ $[CO_2] = 0.05 M$ $[H_2O] = 0.11 M$ $[CO] = 0.11 M$
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