Answer
Ordering elements by their mass numbers is not reliable because some elements have isotopes, meaning they have the same atomic numbers, but different mass numbers because of differing numbers of neutrons. Ordering by mass will not be as consistent as ordering by atomic number.
Work Step by Step
Ordering elements by their mass numbers is not reliable because some elements have isotopes, meaning they have the same atomic numbers, but different mass numbers because of differing numbers of neutrons. Ordering by mass will not be as consistent as ordering by atomic number.