Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 17 - Electrochemistry and Its Applications - Problem Solving Practice 17.6 - Page 761: a

Answer

The reaction is product-favored.

Work Step by Step

We need to check if the $E^{\circ}_{cell}$ value is positive or negative. Positive $E^{\circ}_{cell}$ value indicates that the reaction is product-favored and negative value indicates that it is reactant-favored. Reduction half-reaction at the cathode is $Hg^{2+}(aq)+2e^{-}\rightarrow Hg(l)$ Oxidation half-reaction at the anode is $2I^{-}(aq)\rightarrow I_{2}(s)+2e^{-} $ $E^{\circ}_{cell}=E^{\circ}_{cathode}-E^{\circ}_{anode}$ $=0.8535\,V-0.535\,V$ (values from table 17.1) $=+0.319\,V$ Value of $E^{\circ}_{cell}$ is positive and therefore the reaction is product-favored.
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