Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Questions for Review and Thought - Topical Questions - Page 693a: 27a

Answer

$0.10mol$ $CH_3COOH$ wouldn't form a buffer with 1L of $0.20M$ $ NaOH$. - Since this solution doesn't have any significant acid, it can't act as a buffer, because, it can't neutralize an added base.

Work Step by Step

- There is a weak acid and a strong base, so we have to consider their reaction: $CH_3COOH(aq) + NaOH(aq) \lt -- \gt CH_3COO^-(aq) + Na^+(aq) + H_2O(l)$ - The limiting reactant is $CH_3COOH$ (0.10 mol), so these are the final concentrations: $CH_3COOH: 0.10 - 0.10 = 0$ $NaOH: 0.20 - 0.10 = 0.10 moles$ $CH_3COO^-: 0 + 0.10 = 0.10 moles$ - Since this solution doesn't have any significant acid, it can't act as a buffer, because, it can't neutralize an added base.
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