Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Questions for Review and Thought - General Questions - Page 693d: 85b

Answer

The pH of this buffer is equal to $4.95$.

Work Step by Step

1. Calculate the pKa value for $CH_3COOH$. $pKa = -log(Ka)$ $pKa = -log( 1.8 \times 10^{- 5})$ $pKa = 4.745$ 2. Check if the ratio is between 0.1 and 10: - $\frac{[Base]}{[Acid]} = \frac{0.241}{0.15}$ - 1.607: It is. 3. Check if the compounds exceed the $K_a$ by 100 times or more: - $ \frac{0.241}{1.8 \times 10^{-5}} = 1.339\times 10^{4}$ - $ \frac{0.15}{1.8 \times 10^{-5}} = 8333$ 4. Using the Henderson–Hasselbalch equation: $pH = pKa + log(\frac{[Base]}{[Acid]})$ $pH = 4.745 + log(\frac{0.241}{0.15})$ ** We calculated the concentration of the base in 85a. $pH = 4.745 + 0.2059$ $pH = 4.95$
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