Chemistry: The Molecular Science (5th Edition)

Published by Cengage Learning
ISBN 10: 1285199049
ISBN 13: 978-1-28519-904-7

Chapter 15 - Additional Aqueous Equilibria - Problem Solving Practice 15.2 - Page 658: a

Answer

The ratio of $[HP{O_4}^{2-}]$ to $[H_2P{O_4}^-]$ is equal to: 1.6.

Work Step by Step

1. Calculate $[H_3O^+]$: $[H_3O^+] = 10^{-pH}$ $[H_3O^+] = 10^{- 7.40}$ $[H_3O^+] = 3.981 \times 10^{- 8}$ 2. Write the $K_a$ equation, and find the ratio: $K_a = \frac{[H_3O^+][HP{O_4}^{2-}]}{[H_2P{O_4}^-]}$ $6.3 \times 10^{-8} = \frac{3.981 \times 10^{-8}*[HP{O_4}^{2-}]}{[H_2P{O_4}^-]}$ $\frac{6.3 \times 10^{-8}}{3.981 \times 10^{-8}} = \frac{[HP{O_4}^{2-}]}{[H_2P{O_4}^-]}$ $1.6 = \frac{[HP{O_4}^{2-}]}{[H_2P{O_4}^-]}$
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