Chemistry: Molecular Approach (4th Edition)

Published by Pearson
ISBN 10: 0134112830
ISBN 13: 978-0-13411-283-1

Chapter 25 - Section 25.5 - Bonding in Coordination Compounds - For Practice - Page 1145: 25.8

Answer

288 kJ/mol

Work Step by Step

Because the solution is yellow, we can deduce that purple light is absorbed since purple is the complementary color to yellow. The color purple ranges from 400 to 430 nm, so we can estimate the average wavelength as 415 nm. Energy corresponding to this wavelength is equal to the crystal field splitting energy $\Delta$. That is, $\Delta= \frac{hc}{\lambda}=\frac{(6.626\times10^{-34}\,J\cdot s) (3.00\times10^{8}\,m/s)}{415\times10^{-9}\,m}$ $=4.78988\times10^{-19}\, J$ In kJ/mol, $\Delta=4.78988\times10^{-19}\, J\times\frac{kilo}{1000}\times\frac{6.02\times10^{23}}{mol}$ $=288\, kJ/mol$
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