Answer
More heat is evolved from 100 g of ethanol.
Work Step by Step
Since the temperature change is the same:
Water: $4.184\ J/g.K\times 50.0\ g=209.2\ J/K$
Ethanol: $2.46\ J/g.K\times100.0\ g=246\ J/K$
More heat is evolved from 100 g of ethanol.