Answer
$78\%$
Work Step by Step
Atomic weights (g/mol): $Na: 22.990,\ K: 39.098$
In 100.0 mol:
Na: $32\ mol\times22.990\ g/mol=740\ g$
K: $68\ mol\times 39.098\ g/mol=2700\ g$
Total mass: $3440\ g$
Mass percent of K: $2700/3440\times100\%=78\%$