Answer
$AsCu_3S_4$
Work Step by Step
From a sample of 100.0 g:
As: 19.024 g, 74.922 g/mol --> 0.25392 mols
Cu: 48.407 g, 63.546 g/mol --> 0.76176 mols
S: 32.569 g, 32.06g/mol --> 1.0159 mols
Normalizing by the number of mols of As:
As: 0.25392 /0.25392 = 1.0
Cu: 0.76176/0.25392 = 3.0
S: 1.0159/0.25392 = 4.0
Therefore the empirical formula is: $AsCu_3S_4$