Chemistry: A Molecular Approach (3rd Edition)

Published by Prentice Hall
ISBN 10: 0321809246
ISBN 13: 978-0-32180-924-7

Chapter 17 - Sections 17.1-17.9 - Exercises - Problems by Topic - Page 855: 69b

Answer

$2.09\times10^{-26}$

Work Step by Step

$\Delta G^{\circ}=\Sigma n_{p}\Delta G_{f}^{\circ}(products)-\Sigma n_{r}\Delta G_{f}^{\circ}(reactants)$ $=[2\Delta G_{f}^{\circ}(H_{2},g)+\Delta G_{f}^{\circ}(S_{2},g)]-[2\Delta G_{f}^{\circ}(H_{2}S,g)]$ $=[2(0\,kJ/mol)+(79.7\,kJ/mol)]-[2(-33.4\,kJ/mol)]$ $=146.5\,kJ/mol$ $\Delta G^{\circ}=-RT\ln K\implies \ln K=-\frac{\Delta G^{\circ}}{RT}$ $=-\frac{146.5\times10^{3}\,J/mol}{(8.314\,Jmol^{-1}K^{-1})(25+273)K}=-59.13$ Then, $K=e^{-59.13}=2.09\times10^{-26}$
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