Chemistry 10th Edition

Published by Brooks/Cole Publishing Co.
ISBN 10: 1133610668
ISBN 13: 978-1-13361-066-3

Chapter 4 - The Structure of Atoms - Exercises - Quantum Numbers and Atomic Orbitals - Page 169: 89

Answer

a) $l$ can be $0$, $1$, $2$ or $3$; b) 1) $3$ 2) $3$ 3) $1$ 4) $1$

Work Step by Step

a) Angular quantum number has to be between $0$ and $n-1$, so for $n=3$, possible options for $l$ are $0$, $1$, $2$ and $3$. b) 1) If $n=3$ and $l=1$, allowed values for magnetic quantum number are $-1$, $0$ and $1$, so there can be only $3$ orbitals with such principal and angular quantum numbers ($3p_{x}$, $3p_{y}$ and $3p_{z}$). 2) As shown in the previous example, allowed values for magnetic quantum number are $-1$, $0$ and $1$, so there can be only $3$ orbitals with such principal and angular quantum numbers ($2p_{x}$, $2p_{y}$ and $2p_{z}$). 3) There is only one orbital with this combination of quantum numbers, and that is $3p_{x}$. 4) If $n=1$, the only value angular quantum number can take is $0$, which implies that the only possible value for magnetic quantum number is also $0$. Hence, there is only one orbital with principal quantum number equal to $1$, and that is $1s$ orbital.
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